Cross-coupling reaction of cyclopropylboronic acid with bromoarenes

被引：62

作者：

Wang, XZ ^{[1
]}

Deng, MZ ^{[1
]}

机构：

[1] ACAD SINICA,SHANGHAI INST ORGAN CHEM,ORGANOMET CHEM LAB,SHANGHAI 200032,PEOPLES R CHINA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1996年 / 22期

关键词：

D O I：

10.1039/p19960002663

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cross-coupling reaction of trans-2-butylcyclopropylboronic acid with bromoarenes proceeds readily in the presence of Pd(PPh(3))(4) and K3PO4 . 3H(2)O to give stereo-defined trans-2-butylcyclopropylarenes in high yields.

引用

页码：2663 / 2664

页数：2

共 18 条

[1] CATECHOLBORANE (1,3,2-BENZODIOXABOROLE) AS A NEW, GENERAL MONOHYDROBORATION REAGENT FOR ALKYNES - CONVENIENT SYNTHESIS OF ALKENEBORONIC ESTERS AND ACIDS FROM ALKYNES VIA HYDROBORATION [J].

BROWN, HC ;

GUPTA, SK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (12) :4370-&

[2] ORGANOBORANES .37. SYNTHESIS AND PROPERTIES OF (Z)-1-ALKENYLBORONIC ESTERS [J].

BROWN, HC ;

IMAI, T .

ORGANOMETALLICS, 1984, 3 (09) :1392-1395

[3] ORGANOBORANES .30. CONVENIENT PROCEDURES FOR THE SYNTHESIS OF ALKYLBORONIC AND ALKENYLBORONIC ACIDS AND ESTERS [J].

BROWN, HC ;

BHAT, NG ;

SOMAYAJI, V .

ORGANOMETALLICS, 1983, 2 (10) :1311-1316

[4]

COLLON JP, 1980, PRINCIPLES APPL ORG

[5]

FONTANI P, 1991, SYNTHESIS-STUTTGART, P605

[6]

HARTLEY FR, 1985, CHEM METAL CARBON BO

[7] ASYMMETRIC CYCLOPROPANATION OF 1-ALKENYLBORONIC ESTERS AND ITS APPLICATION TO THE SYNTHESIS OF OPTICALLY-ACTIVE CYCLOPROPANOLS [J].

IMAI, T ;

MINETA, H ;

NISHIDA, S .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (17) :4986-4988

[8]

KAMABUCHI AA, 1993, SYNTHETIC COMMUN, V23, P2581

[9] PALLADIUM-CATALYZED INTERMOLECULAR AND INTRAMOLECULAR CROSS-COUPLING REACTIONS OF B-ALKYL-9-BORABICYCLO[3.3.1]NONANE DERIVATIVES WITH 1-HALO-1-ALKENES OR HALOARENES - SYNTHESES OF FUNCTIONALIZED ALKENES, ARENES, AND CYCLOALKENES VIA A HYDROBORATION COUPLING SEQUENCE [J].

MIYAURA, N ;

ISHIYAMA, T ;

SASAKI, H ;

ISHIKAWA, M ;

SATOH, M ;

SUZUKI, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (01) :314-321

[10] VINYL DERIVATIVES OF METALS .14. REACTION OF TRIMETHYLVINYL COMPOUNDS OF SILICON, GERMANIUM, AND TIN WITH IODOMETHYLZINC IODIDE - PREPARATION OF CYCLOPROPYLTIN COMPOUNDS BY GRIGNARD PROCEDURE [J].

SEYFERTH, D ;

COHEN, HM .

INORGANIC CHEMISTRY, 1962, 1 (04) :913-&

← 1 2 →