Analysis of C=O•••H-O interactions in organic crystal structures

被引：50

作者：

Grabowski, SJ ^{[1
]}

机构：

[1] Univ Bialystok, Inst Chem, PL-15443 Bialystok, Poland

来源：

TETRAHEDRON | 1998年 / 54卷 / 34期

关键词：

D O I：

10.1016/S0040-4020(98)00607-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An analysis is given of C=O..H-O interactions in neutron diffraction organic crystal structures taken from Cambridge Structural Database. The dependence of the H..O intermolecular distance on the C=O bond length supports the concept of the valence sum rule. It was found that the Lewis-base strengths of C=O groups are close to the Lewis-acid strengths of O-H bonds within such systems. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：10153 / 10160

页数：8

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