Electrochemical lithium doping of a pentacene molecule semiconductor

被引:23
作者
Fang, B [1 ]
Zhou, H [1 ]
Honma, I [1 ]
机构
[1] AIST, Inst Energy Technol, Nanoenergy Mat Grp, Tsukuba, Ibaraki 3058568, Japan
关键词
D O I
10.1063/1.1954873
中图分类号
O59 [应用物理学];
学科分类号
摘要
Li-doped pentacene has been developed by using an electrochemical approach; that is, constant-potential electrolysis. Li-doped pentacene was characterized by Raman spectrometry and x-ray diffraction measurements. Lithium doping introduces a modification of the C-H vibrational modes located at the end of pentacene molecules. A low doping level has been observed for electrochemical synthesis of Li-doped pentacene, and lithium species are supposed to be intercalated between the two-dimensional pentacene layers. The lithium-doped pentacene exhibits a conductivity of similar to 6x10(-3) S cm(-1).
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页码:1 / 3
页数:3
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