Electrochemical impedance measurements for the investigation of odorants interaction with thiol layer immobilized onto gold electrode

被引:12
作者
Szymanska, I [1 ]
Radecka, H [1 ]
Radecki, J [1 ]
机构
[1] Polish Acad Sci, Inst Anim Reprod & Food Res, Div Food Sci, PL-10747 Olsztyn, Poland
关键词
impedance; gold electrode modified by thiol layers; odorants;
D O I
10.1016/S0925-4005(01)00541-X
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The impedance measurements were used for the detection of the interaction of smell compounds with thiol layer deposited onto gold electrode. The following compounds were selected for the study: geraniol, coumarin, menthol, 1-octanol, beta -ionone. The changes of the resistance and capacitance of the thiol layer, occurred under stimulation by odorants, calculated on the base of impedance measurements, were correlated with other parameters describing physico-chemical properties (partition coefficients log P) and topological one such as total surface area (TSA) and van der Waals ' Volume (VDW). (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:95 / 100
页数:6
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