Solution-Processed Nanostructured Benzoporphyrin with Polycarbonate Binder for Photovoltaics

被引:37
作者
Ku, Sung-Yu [1 ]
Liman, Christopher D. [1 ]
Cochran, Justin E. [2 ]
Toney, Michael F. [3 ]
Chabinyc, Michael L. [1 ]
Hawker, Craig J. [1 ]
机构
[1] Univ Calif Santa Barbara, Mat Res Lab, Dept Mat, Mitsubishi Chem Ctr Adv Mat, Santa Barbara, CA 93106 USA
[2] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
[3] Stanford Synchrotron Radiat Lab, Stanford, CA 94305 USA
基金
美国国家科学基金会;
关键词
CARBON-DIOXIDE; SOLAR-CELLS; EFFICIENT; POLYMERS;
D O I
10.1002/adma.201100028
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A new method to aid large-area solution processing of organic small molecule semiconductors is reported. A thermally degradable poly(propylene carbonate) (PC) binder is added to a solution of soluble precursor to a tetrabenzoporphyrin to increase its viscosity, allowing for the use of large-area methods such as inkjet printing, slot coating, or blade coating. This method is used to make bulk heterojunction solar cells with a p-i-n type structure.
引用
收藏
页码:2289 / +
页数:6
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