Simulating the dissolution and growth of zeolite beta C

被引：23

作者：

Chiu, ME

Slater, B

Gale, JD

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] UCL Royal Inst Great Britain, Davy Faraday Res Lab, London W1S 4BS, England

[3] Curtin Univ Technol, Dept Appl Chem, Nanochem Res Inst, Perth, WA 6845, Australia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 08期

关键词：

crystal growth; solid-state structures; solvent effects; surface chemistry; zeolites;

D O I：

10.1002/anie.200461545

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

A simple model of zeolite growth and dissolution has been constructed. Lattice-energy calculations suggest that both growth and dissolution, progressing through attachment or leaching of monomeric units, involves a number of exothermic and endothermic steps. Oligomeric units may play a key role in overcoming the most endothermic (rate-determining) steps of crystal growth associated with the pictured high-energy structure. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1213 / 1217

页数：5

共 28 条

[1]

[Anonymous], ANGEW CHEM

[2]

Supramolecular self-assembled molecules as organic directing agent for synthesis of zeolites [J].