Novel two-dimensional sodium molybdenum phosphates containing {M(enMe)2}2+ bridging groups (M = Ni, Cu;: enMe=1,2-diaminopropane)

被引：29

作者：

Huang, RD

Liu, FC

Li, YG

Yuan, M

Wang, EB ^{[1
]}

De, GH

Hu, CW

Hu, NH

Jia, HQ

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Changchun 130024, Jilin, Peoples R China

[2] Beijing Inst Technol, Sch Chem Engn & Mat Sci, Beijing 100081, Peoples R China

[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2003年 / 349卷

基金：

中国国家自然科学基金;

关键词：

molybdenum phosphate; transition metal coordination complexes; hydrothermal synthesis; pillared structure;

D O I：

10.1016/S0020-1693(03)00006-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel organic-inorganic hybrid compounds, (H(2)enMe)(4)(H3O)[Ni(enMe)(2)].[Na3Mo12O52P8(OH)(10)].5H(2)O (1) and (H(2)enMe)(4)(H3O)[Cu(enMe)(2)].[Na3Mo12O52P8(OH)(10)].5H(2)O (2) (enMe = 1,2-diaminopropane), have been hydrothermally synthesized and characterized by elemental analyses, IR, EPR, XPS, UV-Vis spectra and TG analyses. Single crystal X-ray diffraction shows that 1 and 2 are isostructural compounds. Both the compounds exhibit an unusual two-dimensional (2-D) window-like network consisting of one-dimensional (1-D) chains of sodium molybdenum phosphate anions connected by transition metal coordination complexes cations. Compound 1 and 2 represent the first 2-D molybdenum phosphate skeleton pillared by transition metal complex fragments. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：85 / 90

页数：6

共 22 条

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