The Baylis-Hillman reaction: a novel source of attraction, opportunities, and challenges in synthetic chemistry

被引:485
作者
Basavaiah, Deevi [1 ]
Rao, Kalapala Venkateswara [1 ]
Reddy, Raju Jannapu [1 ]
机构
[1] Univ Hyderabad, Sch Chem, Hyderabad 500046, Andhra Pradesh, India
关键词
D O I
10.1039/b613741p
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Baylis-Hillman reaction is a successful, useful, and atom-economical carbon-carbon bond forming reaction, which has grown from an obscure level to the level of high synthetic popularity due to its operational simplicity and also due to the enormous applications of the Baylis-Hillman adducts in organic synthesis. In this tutorial review, we briefly describe the way this reaction has grown to its present heights and the opportunities, attractions, and challenges the reaction offers with respect to its asymmetric and intramolecular versions, and mechanistic aspects.
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页码:1581 / 1588
页数:8
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