N-[2-(N′-hydroxy-N-oxidodiaziniumyl)-3-methylbutyl]octanamide

被引：2

作者：

Chang, RW ^{[1
]}

Shin, WC

机构：

[1] Seoul Natl Univ, Dept Chem, Seoul 151742, South Korea

[2] Seoul Natl Univ, Ctr Mol Catalysis, Seoul 151742, South Korea

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷

关键词：

D O I：

10.1107/S0108270198000729

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, C13H27N3O3, exists in the N'-hydroxy-N-oxidodiaziniumyl [R-N(O)=N-OH] form instead of the tautomeric N-hydroxy-N'-nitrosoamino [R-N(OH)-N-O] form. Variation of the bond distances and good planarity indicate that resonance takes place in the [N2O2]H moiety, The molecule assumes an overall elongated conformation. Two centrosymmetrically-related molecules form a dimer via two three-centered N1-H ... O-2/O-3 hydrogen bonds. Crystal packing consists of alternating hydrophilic and hydrophobic layers.

引用

页码：827 / 829

页数：3

共 8 条

[1] STRUCTURE OF ANTICANCER ANTIBIOTIC L-ALANOSINE
JALAL, MAF
HOSSAIN, MB
VANDERHELM, D
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1986, 42 : 733 - 738
[2] Johnson C. K., 1976, ORNL5138
[3] ALANOSINE A NEW ANTIVIRAL AND ANTITUMOUR AGENT ISOLATED FROM A STREPTOMYCES
MURTHY, YKS
THIEMANN, JE
CORONELL.C
SENSI, P
[J]. NATURE, 1966, 211 (5054) : 1198 - &
[4] SECONDARY AMINE NITRIC-OXIDE COMPLEX-IONS, R2N[N(O)NO]- - O-FUNCTIONALIZATION CHEMISTRY
SAAVEDRA, JE
DUNAMS, TM
FLIPPENANDERSON, JL
KEEFER, LK
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1992, 57 (23) : 6134 - 6138
[5] SCANLAN RA, 1981, AM CHEM SOC S SER, V174
[6] PHASE ANNEALING IN SHELX-90 - DIRECT METHODS FOR LARGER STRUCTURES
SHELDRICK, GM
[J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1990, 46 : 467 - 473
[7] SHELDRICK GM, 1993, SHELXL93 PROGRAM REF
[8] YOON TS, 1994, P AM CRYST ASS M ATL

← 1 →