A building block approach to the synthesis of organic-inorganic oxide materials:: the hydrothermal synthesis and network structure of [{Ni4(tpypyz)3}{Mo5O15(O3PCH2CH2PO3)}2]•23H2O (tpypyz = tetra-2-pyridylpyrazine)

被引：109

作者：

Burkholder, E

Golub, V

O'Connor, CJ

Zubieta, J ^{[1
]}

机构：

[1] Syracuse Univ, Dept Chem, Syracuse, NY 13244 USA

[2] Univ New Orleans, Dept Chem, New Orleans, LA 70148 USA

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 17期

关键词：

D O I：

10.1039/b303659f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The hydrothermal reaction of MoO3, [Ni(CH3CO2)(2)] . 4H(2)O, tpypyz, ethylenediphosphonic acid and water yields the 2D material [{Ni-4(tpypyz)(3)}{Mo5O15(O3PCH2CH2PO3)}(2)] . 23H(2)O (1 . 23H(2)O), constructed from {Mo5O15(O3PCH2CH2PO3)}(4-) clusters linked in one-dimension through the ethylene tethers of the diphosphonate component; these molybdodiphosphonate chains are in turn linked into a 2D network through the tetranuclear secondary metal - ligand subunit {Ni-4(tpypyz)(3)}(8+).

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页码：2128 / 2129

页数：2

相关论文

共 12 条

[1]

BURKHOLDER E, 2003, IN PRESS INORG CHEM, V42

[2] New solids from old clusters: Syntheses and structure of [Cu(en)(2)](2)[Mo8O26], [Cu(enMe)(2)](3)[V15O36Cl].2.5H(2)O and Cs-0.5[Ni(en)(2)](3)[V18O42Cl].2en.6H(2)O [J].

DeBord, JRD ;

Haushalter, RC ;

Meyer, LM ;

Rose, DJ ;

Zapf, PJ ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 1997, 256 (02) :165-168

[3] Organic-inorganic hybrid materials:: Hydrothermal syntheses and structural characterization of bimetallic organophosphonate oxides of the type Mo/Cu/O/RPO32-/organoimine [J].

Finn, RC ;

Rarig, RS ;

Zubieta, J .

INORGANIC CHEMISTRY, 2002, 41 (08) :2109-2123

[4] The hydrothermal syntheses and characterization of one- and two-dimensional structures constructed from metal-organic derivatives of polyoxometalates:: [{Cu(bpy)2}{Cu(bpy)(H2O)}(Mo5O15){O3P(CH2)4PO3}]•H2O and [{Cu2(tpypyz)(H2O)2}(Mo5O15)(O3PCH2CH2PO3)]•5.5H2O [bpy=2,2′-bipyridine, tpypyz = tetra(2-pyridyl)pyrazine] [J].

Finn, RC ;

Burkholder, E ;

Zubieta, J .

CHEMICAL COMMUNICATIONS, 2001, (18) :1852-1853

[5]

Greenwood N.N., 1984, CHEM ELEMENTS

[6] Polyoxomolybdate clusters and copper-organonitrogen complexes as building blocks for the construction of composite solids [J].

Hagrman, D ;

Hagrman, P ;

Zubieta, J .

INORGANICA CHIMICA ACTA, 2000, 300 :212-224

[7] STABLE ORGANIC DERIVATIVES OF HETEROPOLY ANIONS, PENTAMOLYBDOBISPHOSPHONATES [J].

KWAK, W ;

POPE, MT ;

SCULLY, TF .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (20) :5735-5738

[8]

MCCARROLL WH, 1994, ENCY INORGANIC CHEM, V6, P2903

[9] [{Mo-VI(8)V-IV(4)O-36(V-VO4)(V-IVO)(2)}(n)](7n-): capped alpha-Keggin fragments linked to a chain [J].

Muller, A ;

Koop, M ;

Schiffels, P ;

Bogge, H .

CHEMICAL COMMUNICATIONS, 1997, (18) :1715-1716

[10] TURNING DOWN THE HEAT - DESIGN AND MECHANISM IN SOLID-STATE SYNTHESIS [J].

STEIN, A ;

KELLER, SW ;

MALLOUK, TE .

SCIENCE, 1993, 259 (5101) :1558-1564