A method for rhodium(II)-catalyzed aziridination of olefins

被引：143

作者：

Muller, P

Baud, C

Jacquier, Y

机构：

[1] Dept. de Chimie Organique, Univ. de Genève, CH-1211 Genève, 30, Quai Ernest Ansermet

来源：

TETRAHEDRON | 1996年 / 52卷 / 05期

关键词：

D O I：

10.1016/0040-4020(95)00999-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The [Rh-2(OAc)(4)] catalyzed decomposition of (N-(p-nitrobenzenesulfonyl)imino)phenyliodinane (PhI=NNs) in the presence of olefins affords aziridines In yields of 18-85%. The aziridination of cis-beta-methylstyrene (1h) and cis-hex-2-ene (1k) is stereospecific. However, with cis-stilbene (Im) a ca 3:1 mixture of cis- and trans aziridines 2m and 2l is obtained. With chiral catalysts asymmetric inductions in up to 73% ee are obtained.

引用

收藏

页码：1543 / 1548

页数：6

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