New developments in radical chemistry.: Applications to total synthesis and asymmetric processes

被引：15

作者：

Aïssa, C ^{[1
]}

Delouvrié, B ^{[1
]}

Dhimane, AL ^{[1
]}

Fensterbank, L ^{[1
]}

Malacria, M ^{[1
]}

机构：

[1] Univ Paris 06, Lab Chim Organ Synthese, F-75005 Paris 05, France

来源：

PURE AND APPLIED CHEMISTRY | 2000年 / 72卷 / 09期

关键词：

D O I：

10.1351/pac200072091605

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This article reviews our contribution in the field of radical synthetic chemistry, focusing on cascades relying on the use of propargylic BMDMS ethers and asymmetric synthesis using enantiopure vinylsulfoxides.

引用

页码：1605 / 1613

页数：9

共 26 条

[1]

AGNEL G, 1989, SYNTHESIS-STUTTGART, P687

[2] CHEMOSELECTIVITY OF THE INTRAMOLECULAR RADICAL-ADDITION BETWEEN TRIPLE AND DOUBLE-BOND .4. [J].

AGNEL, G ;

MALACRIA, M .

TETRAHEDRON LETTERS, 1990, 31 (25) :3555-3558

[3] 5-endo-trig radical cyclizations of bromomethyldimethylsilyl diisopropylpropargylic ethers.: A highly diastereoselective access to functionalized cyclopentanes [J].

Bogen, S ;

Gulea, M ;

Fensterbank, L ;

Malacria, M .

JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (13) :4920-4925

[4] 5-endo-trig Radical cyclizations: A new means to the stereoselective synthesis of cyclopentanes and diquinanes [J].

Bogen, S ;

Malacria, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (16) :3992-3993

[5]

BOGEN S, 1994, SYNLETT, P958

[6]

Bogen S, 1997, RRD ORG CHEM, V1, P385

[7] Unprecedented radical cyclizations cascade leading to bicyclo[3.1.1]heptanes. Toward a new generation of radical cascades [J].

Bogen, S ;

Fensterbank, L ;

Malacria, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (21) :5037-5038

[8] Asymmetric intramolecular radical vinylation using enantiopure sulfoxides as temporary chiral auxiliaries [J].

Delouvrié, B ;

Fensterbank, L ;

Lacôte, E ;

Malacria, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (49) :11395-11401

[9] From acyclic precursors to linear triquinanes through a diastereoselective one-pot process. A new illustration of the synthetic power of radical cascades [J].

Devin, P ;

Fensterbank, L ;

Malacria, M .

JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (20) :6764-6765

[10]

DHIMANE AL, 2000, IN PRESS RADICAL ORG, V2

← 1 2 3 →