Synthesis and structure of a magnesium hydroxide complex supported by tris(pyrazolyl)hydroborato ligation, {[Tp(Ar,Me)]MgC(mu-OH)}(2) (Ar=p-Bu(t)C(6)H(4))

被引：35

作者：

Ghosh, P ^{[1
]}

Parkin, G ^{[1
]}

机构：

[1] COLUMBIA UNIV,DEPT CHEM,NEW YORK,NY 10027

来源：

INORGANIC CHEMISTRY | 1996年 / 35卷 / 06期

关键词：

D O I：

10.1021/ic9515970

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A well-defined magnesium hydroxide complex has been synthesized by using a tris- (pyrazolyl)hydroborato ligand with p-tert-butylphenyl substituents. Specifically, the dinuclear complex {[Tp(Ar,Me)]Mg(mu-OH)}(2) (Ar = p-Bu(t)C(6)H(4)) is prepared by the reaction of the magnesium alkyl derivative [Tp(Ar,Me)]MgMe with H2O.

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页码：1429 / &

页数：3

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