Adiabatic theorems and reversible isothermal processes

被引:20
作者
Abou-Salem, W [1 ]
Fröhlich, J [1 ]
机构
[1] ETH Honggerberg, Inst Theoret Phys, CH-8093 Zurich, Switzerland
关键词
adiabatic theorem; isothermal processes; reversible processes;
D O I
10.1007/s11005-005-4838-1
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
Isothermal processes of a finitely extended, driven quantum system in contact with an infinite heat bath are studied from the point of view of quantum statistical mechanics. Notions like heat flux, work and entropy are defined for trajectories of states close to, but distinct from states of joint thermal equilibrium. A theorem characterizing reversible isothermal processes as quasi-static processes ("isothermal theorem") is described. Corollaries concerning the changes of entropy and free energy in reversible isothermal processes and on the 0th law of thermodynamics are outlined.
引用
收藏
页码:153 / 163
页数:11
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