An air quality survey and emissions inventory at Aberdeen Harbour

A network of 10 stations, with passive sampling for VOCs (including benzene), NO2, and SO2, over 2-week periods, grab sampling for CO, and 48-h pumped sampling for PM10, was set up to make an air quality survey for 12 months around Aberdeen Harbour. Benzene, CO, SO2 and PM10 were always well below the AQS target values. However, NO2 frequently showed a pronounced gradient across the harbour reaching its highest concentrations at the city end, indicating that the road traffic was the principal source of the pollution. This was backed up by the predominance of aromatics in the VOCs in the city centre, derived from petrol engined vehicles, compared to the predominance of alkanes and alkenes around the docks, derived from diesel engined heavy trucks and possibly ships. Black carbon on the PM10 filters also showed a gradient with highest levels in the city centre. It is proposed that for such surveys in future, NO2 and black carbon would be the two most informative parameters. This emissions inventory has shown first, that trucks contribute very little to the total, and second, that the ro-ro ferries are the major contributors as they burn light fuel oil while the oil platform supply vessels burn low-sulphur marine gas oil with around 0.1% S. When the whole picture of the emissions from the city is considered, the emissions from the harbour constitute only a small part. (C) 2007 Elsevier Ltd. All rights reserved.