Reactivity of the metal-cyclopentadienyl (indenyl, fluorenyl and cycloheptatrienyl) bonds

被引：19

作者：

Liu, Ruiting ^{[1
]}

Zhou, Xigeng ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai Key Lab Mol Catalysis & Innovat Mat, Shanghai 200433, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2007年 / 692卷 / 21期

基金：

美国国家科学基金会; 中国国家自然科学基金;

关键词：

insertion; coupling reaction; organometallic complexes; cyclopentadienyl; indenyl; fluorenyl; cycloheptatrienyl;

D O I：

10.1016/j.jorganchem.2007.05.033

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The focus of this review concerns the reactivity patterns of metal-cyclopentadienyl (indenyl, fluorenyl and cycloheptatrienyl) bonds. The advances in the metal-carbon(eta(5)) insertion chemistry have demonstrated that the pi-bonding character provides additional reaction opportunities which are not shown by metal-alkyl compounds and these differences are highlighted.. (C) 2007 Elsevier B.V. All rights reserved.

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收藏

页码：4424 / 4435

页数：12

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