Senepodines B-E, new C22N2 alkaloids from Lycopodium chinense

被引：26

作者：

Hirasawa, Y ^{[1
]}

Morita, H ^{[1
]}

Kobayashi, J ^{[1
]}

机构：

[1] Hokkaido Univ, Grad Sch Pharmaceut Sci, Sapporo, Hokkaido 0600812, Japan

来源：

TETRAHEDRON | 2003年 / 59卷 / 20期

关键词：

Lycopodium chinense; alkaloids; exciton chirality method;

D O I：

10.1016/S0040-4020(03)00545-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Four new C22N2 Lycopodium alkaloids, senepodines B-E (2-5), consisting of an octahydroquinoline ring and a quinolizidine ring have been isolated together with senepodine A (1) from the club moss Lycopodium chinense. The relative and absolute stereochemistry of 2-5 were determined by combination of NOESY correlations and chemical transformation, while the absolute configuration of 1 was assigned by exciton chirality method. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：3567 / 3573

页数：7

共 26 条

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