Chelating bis(thiophosphinic amidate)s as versatile supporting ligands for the group 3 metals. An application to the synthesis of highly active catalysts for intramolecular alkene hydroamination

被引：174

作者：

Kim, YK ^{[1
]}

Livinghouse, T ^{[1
]}

Horino, Y ^{[1
]}

机构：

[1] Montana State Univ, Dept Chem, Bozeman, MT 59717 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 32期

关键词：

D O I：

10.1021/ja021445l

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bis(thiophosphinic amidate) complexes (i.e., 1) of representative group 3 and lanthanide metals have been quantiatively prepared in situ from the corresponding thiophosphinic amides and Ln[N(TMS)2]3. These unusual pentacoordinate complexes exhibit very high activity as catalysts for intramolecular alkene hydroamination. Copyright © 2003 American Chemical Society.

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页码：9560 / 9561

页数：2

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