C59N+:: A key intermediate in azaheterofullerene chemistry

被引：44

作者：

Hauke, F ^{[1
]}

Hirsch, A ^{[1
]}

机构：

[1] Inst Organ Chem, D-91054 Erlangen, Germany

来源：

TETRAHEDRON | 2001年 / 57卷 / 17期

关键词：

fullerenes; azaheterofullerenes; Mannich reaction; enols;

D O I：

10.1016/S0040-4020(01)00235-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The thermal treatment of the azaheterofullerene dimer (C59N)(2) in the presence of oxygen and a nucleophilic trapping reagent leads to the facile and selective formation of a variety of monomeric adducts C59NR involving electronic rich aromatics, carbonyl compounds, alcohols and olefins as terminating addend. These investigations within the field of synthetic heterofullerene chemistry imply the presence of C59N1 as an important key intermediate. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：3697 / 3708

页数：12

共 8 条

[1] Synthesis of C-59(CHPh(2))N from (C59N)(2) and C59HN. The first derivatization of C59N [J].