Photochromism of a dithienylethene having diphenylamino side groups in the bulk amorphous phase

被引:20
作者
Fukudome, M
Kamiyama, K
Kawai, T
Irie, M
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Higashi Ku, Fukuoka 8128581, Japan
[2] Japan Sci & Technol Corp, JST, CREST, Higashi Ku, Fukuoka 8128581, Japan
[3] Kyocera Corp Ltd, Ctr Res & Dev, Kagoshima 8994312, Japan
关键词
D O I
10.1246/cl.2001.70
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
1,2-Bis(2,4-dimethyl-5-phenyl-3-thienyl)perfluorocyclo- pentene was found to form an amorphous state in bulk by introducing diphenylamino substituents at both ends of the molecule, The glass transition temperature was as high as 103 degreesC. The amorphous film exhibited reversible color and refractive index changes by alternate irradiation with ultraviolet and visible light.
引用
收藏
页码:70 / 71
页数:2
相关论文
共 18 条
[1]   Photoinduced manipulations of photochromes in polymers: Anisotropy, modulation of the NLO properties and creation of surface gratings [J].
Atassi, Y ;
Chauvin, J ;
Delaire, JA ;
Delouis, JF ;
Fanton-Maltey, I ;
Nakatani, K .
PURE AND APPLIED CHEMISTRY, 1998, 70 (11) :2157-2166
[2]   Large and stable refractive index change in photochromic hybrid materials [J].
Biteau, J ;
Chaput, F ;
Lahlil, K ;
Boilot, JP ;
Tsivgoulis, GM ;
Lehn, JM ;
Darracq, B ;
Marois, C ;
Levy, Y .
CHEMISTRY OF MATERIALS, 1998, 10 (07) :1945-1950
[3]   Photochromism of dithienylethene derivatives trapped in sol-gel matrices [J].
Biteau, J ;
Tsivgoulis, GM ;
Chaput, F ;
Boilot, JP ;
Gilat, S ;
Kawai, S ;
Lehn, JM ;
Darracq, B ;
Martin, F ;
Levy, Y .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1997, 297 :65-72
[4]  
FUKUDOME M, 2000, 78 SPRING M CHEM SOC
[5]   THERMALLY IRREVERSIBLE PHOTOCHROMIC SYSTEMS - REVERSIBLE PHOTOCYCLIZATION OF DIARYLETHENE DERIVATIVES [J].
IRIE, M ;
MOHRI, M .
JOURNAL OF ORGANIC CHEMISTRY, 1988, 53 (04) :803-808
[6]   Diarylethenes for memories and switches [J].
Irie, M .
CHEMICAL REVIEWS, 2000, 100 (05) :1685-1716
[7]   Photochromism of dithienylethenes with electron-donating substituents [J].
Irie, M ;
Sakemura, K ;
Okinaka, M ;
Uchida, K .
JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (25) :8305-8309
[8]   Optical properties of photochromic dyes in the amorphous state [J].
Kaneuchi, Y ;
Kawai, T ;
Hamaguchi, M ;
Yoshino, K ;
Irie, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1997, 36 (6A) :3736-3739
[9]   OPTICAL AND DIELECTRIC-PROPERTIES OF PHOTOCHROMIC DYE IN AMORPHOUS STATE AND ITS APPLICATION [J].
KAWAI, T ;
KOSHIDO, T ;
YOSHINO, K .
APPLIED PHYSICS LETTERS, 1995, 67 (06) :795-797
[10]   Refractive index change of dithienylethene in bulk amorphous solid phase [J].
Kawai, T ;
Fukuda, N ;
Gröschl, D ;
Kobatake, S ;
Irie, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS, 1999, 38 (10B) :L1194-L1196