Flame-excited luminescence in the oxides Ta2O5, Nb2O5, TiO2, ZnO, and SnO2

被引:44
作者
Provenzano, PL [1 ]
Jindal, GR [1 ]
Sweet, JR [1 ]
White, WB [1 ]
机构
[1] Penn State Univ, Mat Res Lab, University Pk, PA 16802 USA
关键词
candoluminescence; oxide phosphors; emission spectra; flame excitation; Nb2O5; Ta2O5; TiO2; SnO2; ZnO;
D O I
10.1016/S0022-2313(00)00264-7
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The flame-excited emission (candoluminescence) of the oxides Ta2O5, Nb2O5, TiO2, ZnO, and SnO2 have been reexamined. By measuring the emission spectra as a function of temperature in comparison with the optical band gap, also measured as a function of temperature, it is concluded that a portion of the emission, particularly in Ta2O5 and Nb2O5, is non-thermal. The results support the hypothesis that the excess emission is due to recombination of electron-hole pairs created by de-excitation of neutral radicals on the phosphor surface. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:297 / 305
页数:9
相关论文
共 13 条
[1]  
CORREDOR A, 1978, RARE EARTHS MODERN S
[2]   OPTICAL-PROPERTIES OF TITANIUM-DIOXIDE IN THE RUTILE STRUCTURE [J].
GLASSFORD, KM ;
CHELIKOWSKY, JR .
PHYSICAL REVIEW B, 1992, 45 (07) :3874-3877
[3]  
HEILAND G, 1959, SOLID STATE PHYS, V8, P151
[4]   CANDOLUMINESCENCE IN TRANSITION-ION-ACTIVATED OXIDE PHOSPHORS [J].
HESS, JW ;
SWEET, JR ;
WHITE, WB .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1974, 121 (01) :142-145
[5]  
Ivey H. F., 1974, Journal of Luminescence, V8, P271, DOI 10.1016/0022-2313(74)90001-5
[6]  
JORGENSEN CK, 1976, STRUCT BOND, V25, P1
[7]   ELECTRONIC SPECTRA OF OXIDES OF LEAD AND OF SOME TERNARY LEAD OXIDE COMPOUNDS [J].
KEESTER, KL ;
WHITE, WB .
MATERIALS RESEARCH BULLETIN, 1969, 4 (10) :757-&
[8]  
NICHOLS EL, 1928, CARNEGIE I WASHINGTO, V384
[9]  
SOKOLOV VA, 1957, B ACAD SCI SSSR PHYS, V21, P525
[10]  
SOKOLOV VA, 1962, B ACAD SCI SSSR PHYS, V26, P571