Antibacterial properties of ruthenium(II) benzamide complexes

被引：19

作者：

Bhowon, MG ^{[1
]}

Laulloo, SJ ^{[1
]}

Ramnial, T ^{[1
]}

机构：

[1] Univ Mauritius, Fac Sci, Dept Chem, Reduit, Mauritius

来源：

TRANSITION METAL CHEMISTRY | 2001年 / 26卷 / 03期

关键词：

D O I：

10.1023/A:1007105021918

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Reactions of the new acyclic ligand DNBH with RuCl3 . 3H(2)O, followed by addition of a secondary ligand L (L = PPh3, 1,10-phenanthroline, 2,2'-bipyridine, pyridine and 2,4-diaminotoluene), yield six binuclear metal complexes, TR1-TR6. Two different methods were employed: template and a two-step synthesis, both yielding the same complexes. DNBH and its metal complexes were characterised by a combination of spectroscopic, elemental and magnetic susceptibility data. Coordination was found to be through the carbonyl oxygen of amide and phenolic oxygen in the octahedral environment of the metal. DNBH and some of the metal complexes display antibacterial properties.

引用

页码：329 / 332

页数：4

共 14 条

[1]

STUDIES ON THE METAL-AMIDE BOND .7. METAL-COMPLEXES OF THE FLEXIBLE N4 LIGAND N,N'-BIS(2'-PYRIDINE-CARBOXAMIDE)1,2-ETHANE [J].