Millisecond reforming of solid biomass for sustainable fuels

被引：85

作者：

Dauenhauer, Paul J. ^{[1
]}

Dreyer, Bradon J. ^{[1
]}

Degenstein, Nick J. ^{[1
]}

Schmidt, Lanny D. ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem Engn & Mat Sci, Minneapolis, MN 55455 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 31期

关键词：

flash pyrolysis; hydrogen; oxidation; rhodium; sustainable chemistry;

D O I：

10.1002/anie.200701238

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Breaking the coke habit: By coupling thermal decomposition with catalytic partial oxidation, an effective method has been developed to convert solid biomass such as cellulose into synthesis gas (see photo of a hot Rh catalyst surface). Not only is the process fast (< 70 ms), it also avoids the formation of coke, which is known to deactivate catalyst surface sites and block surface reactions. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5864 / 5867

页数：4

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