Advanced anodes for high-temperature fuel cells

被引:1352
作者
Atkinson, A [1 ]
Barnett, S
Gorte, RJ
Irvine, JTS
Mcevoy, AJ
Mogensen, M
Singhal, SC
Vohs, J
机构
[1] Univ London Imperial Coll Sci Technol & Med, Dept Mat, London SW7 2BP, England
[2] Northwestern Univ, Dept Mat Sci, Evanston, IL 60208 USA
[3] Univ Penn, Dept Chem Engn, Philadelphia, PA 19104 USA
[4] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland
[5] Ecole Polytech Fed Lausanne, ICMB, FSB, CH-1015 Lausanne, Switzerland
[6] Riso Natl Lab, Mat Res Dept, DK-4000 Roskilde, Denmark
[7] Pacific NW Natl Lab, Richland, WA 99352 USA
基金
美国国家科学基金会;
关键词
D O I
10.1038/nmat1040
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Fuel cells will undoubtedly find widespread use in this new millennium in the conversion of chemical to electrical energy, as they offer very high efficiencies and have unique scalability in electricity-generation applications. The solid-oxide fuel cell (SOFC) is one of the most exciting of these energy technologies; it is an all-ceramic device that operates at temperatures in the range 500-1,000degreesC. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use carbon monoxide as a fuel rather than being poisoned by it, and the availability of high-grade exhaust heat for combined heat and power, or combined cycle gas-turbine applications. Although cost is clearly the most important barrier to widespread SOFC implementation, perhaps the most important technical barriers currently being addressed relate to the electrodes, particularly the fuel electrode or anode. In terms of mitigating global warming, the ability of the SOFC to use commonly available fuels at high efficiency, promises an effective and early reduction in carbon dioxide emissions, and hence is one of the lead new technologies for improving the environment. Here, we discuss recent developments of SOFC fuel electrodes that will enable the better use of readily available fuels.
引用
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页码:17 / 27
页数:11
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