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Comparison of catalytic properties for partial oxidation between heteropolyacids and phosphates of vanadium and iron
被引:31
作者:
Ai, M
机构:
[1] Dept. of Appl. Chem. and Biotech., Niigata Institute of Technology, Kashiwazaki 945-11
关键词:
molybdophosphoric acid;
vanadyl pyrophosphate;
iron phosphate;
oxidation of alkanes;
oxidation of alkenes;
oxidation of methacrolein;
oxidation of acrolein;
oxidation of crotonaldehyde;
oxidation of isobutyric acid;
oxidation of propionic acid;
oxidation of methanol;
formation of furan;
D O I:
10.1016/S1381-1169(96)00300-7
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
The catalytic properties of heteropoly compounds such as 12-molybdophosphoric acid [H3PMo12O40] and its derivatives for gas-phase partial oxidation of various organic compounds were compared with those of phosphates of transition metals such as vanadium phosphate and iron phosphate. The characteristics of catalysts consisting of heteropoly compounds were elucidated.
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页码:3 / 13
页数:11
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