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Asymmetric addition of aryl boron reagents to enones with rhodium dicyclophane imidazolium carbene catalysis

被引：155
作者：
Ma, YD
Song, C
Ma, CQ
Sun, ZJ
Chai, Q
Andrus, MB [1 ]
机构：
[1] Brigham Young Univ, Dept Chem & Biochem, Provo, UT 84602 USA
[2] Shandong Univ, Chem Coll, Shandong 250100, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 47期
关键词：
addition; boron; cyclophanes; homogeneous catalysis; rhodium;
D O I：
10.1002/anie.200352679
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chiral N-heterocyclic carbene ligands based on [2.2]paracyclophanes form complexes with rhodium. These catalysts can be used in the high-yielding and enantioselective asymmetric conjugate addition of arylboron compounds to cyclic and acyclic enones (see scheme).
引用
收藏
页码：5871 / 5874
页数：4
相关论文
共 54 条
  • [1] Alexakis A, 2000, EUR J ORG CHEM, V2000, P4011, DOI 10.1002/1099-0690(200012)2000:24<4011::AID-EJOC4011>3.0.CO
  • [2] 2-D
  • [3] Palladium-imidazolium carbene catalyzed Mizoroki-Heck coupling with aryl diazonium ions
    Andrus, MB
    Song, C
    Zhang, JQ
    [J]. ORGANIC LETTERS, 2002, 4 (12) : 2079 - 2082
  • [4] Palladium-imidazolium carbene catalyzed aryl, vinyl, and alkyl Suzuki-Miyaura cross coupling
    Andrus, MB
    Song, C
    [J]. ORGANIC LETTERS, 2001, 3 (23) : 3761 - 3764
  • [5] Looking for stable carbenes: The difficulty in starting anew
    Arduengo, AJ
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (11) : 913 - 921
  • [6] Rhodium-catalyzed asymmetric conjugate additions of boronic acids using monodentate phosphoramidite ligands
    Boiteau, JG
    Imbos, F
    Minnaard, AJ
    Feringa, BL
    [J]. ORGANIC LETTERS, 2003, 5 (05) : 681 - 684
  • [7] Synthesis of iridium complexes with novel planar chiral chelating imidazolylidene ligands
    Bolm, C
    Focken, T
    Raabe, G
    [J]. TETRAHEDRON-ASYMMETRY, 2003, 14 (12) : 1733 - 1746
  • [8] Planar and central chiral [2.2] paracyclophane-based N,O-ligands as highly active catalysts in the diethylzinc addition to aldehydes
    Dahmen, S
    Bräse, S
    [J]. CHEMICAL COMMUNICATIONS, 2002, (01) : 26 - 27
  • [9] Novel chiral tridentate Schiff base ligands of the [2.2]paracyclophane series:: synthesis and application
    Danilova, TI
    Rozenberg, VI
    Sergeeva, EV
    Starikova, ZA
    Bräse, S
    [J]. TETRAHEDRON-ASYMMETRY, 2003, 14 (14) : 2013 - 2019
  • [10] Enders D, 2002, ANGEW CHEM INT EDIT, V41, P1743, DOI 10.1002/1521-3773(20020517)41:10<1743::AID-ANIE1743>3.0.CO
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