Enantioselective inclusion in bile acids: resolution of cyclic ketones

被引:28
作者
Bertolasi, V [1 ]
Bortolini, O [1 ]
Fogagnolo, M [1 ]
Fantin, G [1 ]
Pedrini, P [1 ]
机构
[1] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy
关键词
D O I
10.1016/S0957-4166(01)00243-9
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Cholic and deoxycholic acids were found to form inclusion compounds with various racemic cyclic ketones enabling direct and straightforward enantiomer separation. The X-ray structure of the 2:1 inclusion complex between (-)-bicyclo[3.2.0]-hept-2-en-6-one and cholic acid is reported. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:1479 / 1483
页数:5
相关论文
共 37 条
  • [1] Enantioselective inclusion of methyl phenyl sulfoxides and benzyl methyl sulfoxides by (R)-phenylglycyl-(R)-phenylglycine and the crystal structures of the inclusion cavities
    Akazome, M
    Ueno, Y
    Ooiso, H
    Ogura, K
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2000, 65 (01) : 68 - 76
  • [2] SIR92 - a program for automatic solution of crystal structures by direct methods
    ALTOMARE, A
    CASCARANO, G
    GIACOVAZZO, G
    GUAGLIARDI, A
    BURLA, MC
    POLIDORI, G
    CAMALLI, M
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 : 435 - 435
  • [3] Optical resolution of sulfoxides by inclusion in host dehydrocholic acid
    Bortolini, O
    Fantin, G
    Fogagnolo, M
    Medici, A
    Pedrini, P
    [J]. CHEMICAL COMMUNICATIONS, 2000, (05) : 365 - 366
  • [4] Resolution of unfunctionalized epoxides by cholic acid inclusion compounds
    Bortolini, O
    Fantin, G
    Fogagnolo, M
    Medici, A
    Pedrini, P
    [J]. CHEMISTRY LETTERS, 2000, (11) : 1246 - 1247
  • [5] CRYSTAL-STRUCTURE AND MULTIPHASE DECOMPOSITION OF A NOVEL CHOLIC-ACID INCLUSION COMPOUND WITH MIXED GUESTS
    CAIRA, MR
    NASSIMBENI, LR
    SCOTT, JL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (07): : 1403 - 1405
  • [6] SELECTIVE INCLUSION BY CHOLIC-ACID
    CAIRA, MR
    NASSIMBENI, LR
    SCOTT, JL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (07) : 612 - 614
  • [7] INCLUSION-COMPOUNDS OF CHOLIC-ACID WITH ALIPHATIC ESTERS
    CAIRA, MR
    NASSIMBENI, LR
    SCOTT, JL
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1994, (03): : 623 - 628
  • [8] ENANTIOSELECTIVELY CATALYZED INTRAMOLECULAR CYCLOPROPANATIONS OF UNSATURATED DIAZO CARBONYL-COMPOUNDS
    DAUBEN, WG
    HENDRICKS, RT
    LUZZIO, MJ
    NG, HP
    [J]. TETRAHEDRON LETTERS, 1990, 31 (48) : 6969 - 6972
  • [9] ENDERS D, 1981, CHEMTECH, V11, P504
  • [10] KINETIC RESOLUTION VIA OXIDATION OF ENDO-BICYCLIC OCTENOLS AND HEPTENOLS WITH BACILLUS-STEAROTHERMOPHILUS
    FANTIN, G
    FOGAGNOLO, M
    MEDICI, A
    PEDRINI, P
    ROSINI, G
    [J]. TETRAHEDRON-ASYMMETRY, 1994, 5 (09) : 1635 - 1638