Nonequilibrium measurements of free energy differences for microscopically reversible Markovian systems

被引：805

作者：

Crooks, GE ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

JOURNAL OF STATISTICAL PHYSICS | 1998年 / 90卷 / 5-6期

关键词：

nonequilibrium statistical mechanics; free energy; work; thermodynamic integration; thermodynamic perturbation;

D O I：

10.1023/A:1023208217925

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

An equality has recently been shown relating the free energy difference between two equilibrium ensembles of a system and an ensemble average of the work required to switch between these two configurations. In the present paper it is shown that this result can be derived under the assumption that the system's dynamics is Markovian and microscopically reversible.

引用

页码：1481 / 1487

页数：7

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