On the mechanism of the photoinduced magnetism in copper octacyanomolybdates

被引：27

作者：

Carvajal, Maria-Angels ^{[1
]}

Reguero, Mar ^{[1
]}

de Graaf, Coen ^{[1
,2
]}

机构：

[1] Univ Rovira & Virgili, Dept Quim Fis & Inorgan, Tarragona 43007, Spain

[2] ICREA, Barcelona 08010, Spain

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 31期

关键词：

PHOTOMAGNETISM; MOLECULE; CLUSTERS;

D O I：

10.1039/c0cc00792g

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

Ab initio calculations show that a possible mechanism for the photomagnetism in copper octacyanomolybdate compounds consists of the initial excitation of the diamagnetic Cu-II-MoIV-CS pair to a Cu-II-MoIV-T state, whose geometry relaxation stabilizes the magnetic doublet and quartet states.

引用

页码：5737 / 5739

页数：3

共 21 条

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