Palladium-catalyzed coupling reaction of 4-alkylnitrobenzenes with aryl bromides at their benzylic position

被引:36
作者
Inoh, J [1 ]
Satoh, T [1 ]
Pivsa-Art, S [1 ]
Miura, M [1 ]
Nomura, M [1 ]
机构
[1] Osaka Univ, Fac Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
关键词
arylation; catalysis; nitro compounds; palladium and compounds;
D O I
10.1016/S0040-4039(98)00832-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
4-Alkylnitrobenzenes effectively undergo coupling with aryl bromides at their benzylic position in the presence of a palladium catalyst and a base to give the corresponding mono- and/or di-arylated products in good yields. (C) 1998 Elsevier Science Ltd, All rights reserved.
引用
收藏
页码:4673 / 4676
页数:4
相关论文
共 11 条
[1]  
AOYAGI Y, 1992, HETEROCYCLES, V33, P257
[2]   FINE FEATHERS MAKE FINE BIRDS - THE HECK REACTION IN MODERN GARB [J].
DE MEIJERE, A ;
MEYER, FE .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1994, 33 (23-24) :2379-2411
[3]  
GOTTI C, 1997, TETRAHEDRON LETT, V38, P8867
[4]   Palladium-catalyzed direct α-arylation of ketones.: Rate acceleration by sterically hindered chelating ligands and reductive elimination from a transition metal enolate complex [J].
Hamann, BC ;
Hartwig, JF .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (50) :12382-12383
[5]   AROMATIC SUBSTITUENT CONSTANTS FOR STRUCTURE-ACTIVITY CORRELATIONS [J].
HANSCH, C ;
LEO, A ;
UNGER, SH ;
KIM, KH ;
NIKAITANI, D ;
LIEN, EJ .
JOURNAL OF MEDICINAL CHEMISTRY, 1973, 16 (11) :1207-1216
[6]  
Heck R.F., 1985, PALLADIUM REAGENTS O
[7]   Palladium-catalyzed alpha-arylation of ketones [J].
Palucki, M ;
Buchwald, SL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (45) :11108-11109
[8]   Palladium-catalyzed arylation of azole compounds with aryl halides in the presence of alkali metal carbonates and the use of copper iodide in the reaction [J].
Pivsa-Art, S ;
Satoh, T ;
Kawamura, Y ;
Miura, M ;
Nomura, M .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1998, 71 (02) :467-473
[9]   Palladium-catalyzed coupling reaction of salicylaldehydes with aryl iodides via cleavage of the aldehyde C-H bond [J].
Satoh, T ;
Itaya, T ;
Miura, M ;
Nomura, M .
CHEMISTRY LETTERS, 1996, (09) :823-824
[10]   Palladium-catalyzed regioselective mono- and diarylation reactions of 2-phenylphenols and naphthols with aryl halides [J].
Satoh, T ;
Kawamura, Y ;
Miura, M ;
Nomura, M .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (16) :1740-1742