Effect of hydrogenation on the metal-semiconductor phase transition in vanadium dioxide thin films

被引：46

作者：

Andreev, V. N. ^{[1
]}

Kapralova, V. M. ^{[2
]}

Klimov, V. A. ^{[1
]}

机构：

[1] Russian Acad Sci, AF Ioffe Physicotech Inst, R-194021 St Petersburg, Russia

[2] St Petersburg State Univ, R-195251 St Petersburg, Russia

来源：

PHYSICS OF THE SOLID STATE | 2007年 / 49卷 / 12期

关键词：

D O I：

10.1134/S1063783407120177

中图分类号：

O469 [凝聚态物理学];

学科分类号：

070205 ;

摘要：

Hydropgen penetration into thin films of vanadium dioxide from aqueous solutions of mono-, di-, and tribasic alcohols is studied. It is shown that this process is reversible, has a catalytic character, and brings about a lowering, of the metal-semiconductor phase transition temperature. It is established that the phase transition in a hydrogenated HxVO2 film is completely suppressed for x > 0.04.

引用

页码：2318 / 2322

页数：5

共 22 条

[1] Effect of grain sizes on the metal-semiconductor phase transition in vanadium dioxide polycrystalline thin films [J].

Aliev, R. A. ;

Andreev, V. N. ;

Kapralova, V. M. ;

Klimov, V. A. ;

Sobolev, A. I. ;

Shadrin, E. B. .

PHYSICS OF THE SOLID STATE, 2006, 48 (05) :929-934

[2] Effect of vacuum heat treatment on the metal-semiconductor phase transition in thin vanadium dioxide films [J].

Aliev, RA ;

Andreev, VN ;

Klimov, VA ;

Lebedev, VM ;

Nikitin, SE ;

Terukov, EI ;

Shadrin, EB .

TECHNICAL PHYSICS, 2005, 50 (06) :754-757

[3] Effect of synthesis conditions on the metal-semiconductor phase transition in vanadium dioxide thin films [J].

Aliev, RA ;

Klimov, VA .

PHYSICS OF THE SOLID STATE, 2004, 46 (03) :532-536

[4]

Andreev V. N., 1993, Technical Physics Letters, V19

[5] Intercalated hydrogen in yttrium barium cuprate: The state and mobility of a "guest" and modification of the "host" properties [J].

Baikov, YM .

PHYSICS OF THE SOLID STATE, 2000, 42 (06) :1026-1035

[6] The chemical state and the mobility of hydrogen in oxide-hydroxide solids [J].

Baikov, YM .

SOLID STATE IONICS, 1997, 97 (1-4) :471-476

[7]

BORESKOV GK, 1986, HETEROGENEOUS CATALY

[8]

Bugaev A. A., 1987, Soviet Physics - Solid State, V29, P1560

[9]

BUGAEV AA, 1979, METAL SEMICONDUCTOR

[10] INFLUENCE OF ION-BEAM PARAMETERS ON THE ELECTRICAL AND OPTICAL-PROPERTIES OF ION-ASSISTED REACTIVELY EVAPORATED VANADIUM DIOXIDE THIN-FILMS [J].

CASE, FC .

JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1987, 5 (04) :1762-1766

← 1 2 3 →