Cyclopentene oxidation with H2O2 over Ti-containing zeolites

被引：52

作者：

Hulea, V

Dumitriu, E

Patcas, F

Ropot, R

Graffin, P

Moreau, P

机构：

[1] Tech Univ Jassy, Catalysis Lab, Fac Ind Chem, R-6600 Jassy, Romania

[2] Ecole Natl Super Chim Montpellier, Lab Mat Catalyt & Catalyse Chim Organ, F-34053 Montpellier, France

来源：

APPLIED CATALYSIS A-GENERAL | 1998年 / 170卷 / 01期

关键词：

cyclopentene; epoxidation; hydrogen peroxide; TS-1; Ti-beta;

D O I：

10.1016/S0926-860X(98)00047-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Ti-containing zeolites TS-1 and Ti-beta are investigated as catalysts for the oxidation of cyclopentene with dilute hydrogen peroxide in organic solvents, at 313 K. Under the same conditions TS-1 is more active than Ti-beta catalyst. It is shown that the activity and selectivity of the system H2O2/Ti-zeolite in this reaction greatly depend on the nature of the solvent (protic or aprotic). (C) 1998 Elsevier Science B.V.

引用

页码：169 / 175

页数：7

共 55 条

[51] SYNTHESIS, CHARACTERIZATION, AND CATALYTIC PROPERTIES OF TITANIUM SILICOALUMINOPHOSPHATE TAPSO-5 [J].