Double inversion of emulsions by using nanoparticles and a di-chain surfactant

被引:155
作者
Binks, Bernard P. [1 ]
Rodrigues, Jhonny A. [1 ]
机构
[1] Univ Hull, Dept Chem, Surfactant & Colloid Grp, Kingston Upon Hull HU6 7RX, N Humberside, England
关键词
emulsion inversion; flocculation; nanoparticles; silica; surfactants;
D O I
10.1002/anie.200700880
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Two shakes: Double phase inversion of emulsions stabilized by a mixture of silica nanoparticles and a di-chain cationic surfactant can be induced by surfactant concentration alone. The picture shows emulsions of dodecane and water stabilized by silica nanoparticles (left, unstable), di-chain cationic surfactant (right, oil-in-water), and a mixture of the two (middle, water-in-oil). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5389 / 5392
页数:4
相关论文
共 15 条
[1]   Mechanism of cationic surfactant adsorption at the solid-aqueous interface [J].
Atkin, R ;
Craig, VSJ ;
Wanless, EJ ;
Biggs, S .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2003, 103 (03) :219-304
[2]   Synergistic interaction in emulsions stabilized by a mixture of silica nanoparticles and cationic surfactant [J].
Binks, Bernard P. ;
Rodrigues, Jhonny A. ;
Frith, William J. .
LANGMUIR, 2007, 23 (07) :3626-3636
[3]   EMULSION-TYPE BELOW AND ABOVE THE CMC IN AOT MICROEMULSION SYSTEMS [J].
BINKS, BP .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1993, 71 (02) :167-172
[4]   Influence of particle wettability on the type and stability of surfactant-free emulsions [J].
Binks, BP ;
Lumsdon, SO .
LANGMUIR, 2000, 16 (23) :8622-8631
[5]  
Binks BP., 2006, COLLOIDAL PARTICLES, P1, DOI DOI 10.1017/CBO9780511536670.002
[6]   Colloidosomes: Selectively permeable capsules composed of colloidal particles [J].
Dinsmore, AD ;
Hsu, MF ;
Nikolaides, MG ;
Marquez, M ;
Bausch, AR ;
Weitz, DA .
SCIENCE, 2002, 298 (5595) :1006-1009
[7]   Characterization of adsorption of quaternary ammonium cationic surfactants and their adsolubilization behaviors on silica [J].
Esumi, K ;
Matoba, M ;
Yamanaka, Y .
LANGMUIR, 1996, 12 (09) :2130-2135
[8]   CONTACT ANGLES ON CHARGED SUBSTRATES [J].
FOKKINK, LGJ ;
RALSTON, J .
COLLOIDS AND SURFACES, 1989, 36 (01) :69-76
[9]   THE MECHANISM OF EMULSION STABILIZATION BY SMALL SILICA (LUDOX) PARTICLES [J].
HASSANDER, H ;
JOHANSSON, B ;
TORNELL, B .
COLLOIDS AND SURFACES, 1989, 40 (1-2) :93-105
[10]   Self-organization of the ternary didecyldimethylammonium bromide/octyl-β-D-glucopyranoside/water system [J].
Junquera, E ;
del Burgo, P ;
Boskovic, J ;
Aicart, E .
LANGMUIR, 2005, 21 (16) :7143-7152