Electrochemical alkyl transfer reactions of trialkylborane to carbonyl compounds by use of copper sacrificial anode

被引:7
作者
Choi, JH [1 ]
Youm, JS
Cho, CG
Czae, MZ
Hwang, BK
Kim, JS
机构
[1] Hanyang Univ, Dept Chem, Seoul 133791, South Korea
[2] Taegu Univ, Dept Chem Educ, Taegu 713714, South Korea
关键词
D O I
10.1016/S0040-4039(98)00915-0
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Alkyl groups in trialkylboranes were successfully transferred to carbonyl compounds in the presence of the platinum cathode and copper anode by electrochemical method. The new, mild electrochemical alkyl transfer reaction produced various substituted alcohols in good yields. (C) 1998 Published by Elsevier Science Ltd. All rights reserved.
引用
收藏
页码:4835 / 4838
页数:4
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