Theory provides a clue to accomplish the synthesis of sumanene, C21H12, the prototypical C3v-buckybowl

被引：29

作者：

Priyakumar, UD ^{[1
]}

Sastry, GN ^{[1
]}

机构：

[1] Pondicherry Univ, Dept Chem, Pondicherry 605014, India

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 07期

关键词：

buckybowls; sumanene; trindene; theoretical calculations; heterobuckybowls;

D O I：

10.1016/S0040-4039(00)02249-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two possible synthetic routes, namely a triphenylene route and a trindene route for the synthesis of sumanene, C21H12 (2CH(2)) and trithiasumanene, C18S3H6 (2S) are analyzed in detail. Theoretical calculations unequivocally predict that the synthesis of sumanene may be easily achieved through a trindene route. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：1379 / 1381

页数：3

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