Novel activated carbon-based catalyst for the selective catalytic reduction of nitrogen oxide

被引:39
作者
Gálvez, ME [1 ]
Lázaro, MJ [1 ]
Moliner, R [1 ]
机构
[1] CSIC, Inst Carboquim, Zaragoza 50015, Spain
关键词
activated carbon; selective catalytic reduction; nitrogen oxide; vanadium; low temperature;
D O I
10.1016/j.cattod.2005.02.020
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A series of catalysts prepared with activated carbons, doped with some vanadium compounds including the ashes of a petroleum coke, have shown considerable activity in the reduction of NO in the presence of ammonia, at relatively low temperatures (100-300 degrees C). The presence of 10% (v/v) water vapour caused a considerable decrease in activity. The presence of 200 PPMV Of SO2 in the reactant gas mixture did not appear to cause any depletion of the NO reduction efficiency. Higher NO reduction efficiencies were measured for the catalysts prepared using preoxidised supports. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:142 / 147
页数:6
相关论文
共 32 条
[1]  
AMIDIRIS MD, 1996, J CATAL, V161, P247
[2]   SOME ASPECTS OF THE SURFACE-CHEMISTRY OF CARBON-BLACKS AND OTHER CARBONS [J].
BOEHM, HP .
CARBON, 1994, 32 (05) :759-769
[3]  
Bosh H., 1988, CATAL TODAY, V2, P369
[4]   Chemical and mechanistic aspects of the selective catalytic reduction of NOx by ammonia over oxide catalysts:: A review [J].
Busca, G ;
Lietti, L ;
Ramis, G ;
Berti, F .
APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 18 (1-2) :1-36
[5]   On oxygen chemisorption for characterization of silica-supported vanadium oxide catalysts [J].
Faraldos, M ;
Anderson, JA ;
Banares, MA ;
Fierro, JLG ;
Weller, SW .
JOURNAL OF CATALYSIS, 1997, 168 (01) :110-116
[6]   Present status and perspectives in de-NOx SCR catalysis [J].
Forzatti, P .
APPLIED CATALYSIS A-GENERAL, 2001, 222 (1-2) :221-236
[7]   Manganese supported catalysts for selective catalytic reduction of nitrogen oxides with ammonia - Part 1 - Characterization [J].
Grzybek, T ;
Klinik, J ;
Rogoz, M ;
Papp, H .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1998, 94 (18) :2843-2850
[8]   Supported manganese catalysts for the selective catalytic reduction of nitrogen oxides with ammonia - Part II. Catalytic experiments [J].
Grzybek, T ;
Pasel, J ;
Papp, H .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1999, 1 (02) :341-348
[9]   Combined effect of H2O and SO2 on V2O5/AC catalysts for NO reduction with ammonia at lower temperatures [J].
Huang, ZG ;
Zhu, ZP ;
Liu, ZY .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 39 (04) :361-368
[10]   Is advanced SCR technology at a standstill? A provocation for the academic community and catalyst manufacturers [J].
Hums, E .
CATALYSIS TODAY, 1998, 42 (1-2) :25-35