Lanthanide complexes derived from (R)-1,1′-binaphthyl-2,2′-bis(neopentylamine) -: {Li(THF)4}{Ln[(R)-C20H12N2(C10H22)]2} (Ln = Sm, Yb) -: novel catalysts for enantioselective intramolecular hydroamination

被引：97

作者：

Collin, J ^{[1
]}

Daran, JC

Schulz, E

Trifonov, A

机构：

[1] Univ Paris 11, ICMMO, Lab Catalyse Mol, F-91405 Orsay, France

[2] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

[3] Russian Acad Sci, GA Razuvaev Inst Organomet Chem, Nizhnii Novgorod 603600, Russia

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 24期

关键词：

D O I：

10.1039/b310954b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The complexes {Li(THF)(4)}{Ln[(R)-C20H12N2(C10H22)](2)} (Ln = Sm, Yb) have been synthesized, fully characterized and found to be efficient and enantioselective catalysts for intramolecular hydroamination of 1-(aminomethyl)-1-allylcyclohexane.

引用

页码：3048 / 3049

页数：2

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