A new methodology for the analysis of failure modes in composite materials by means of acoustic emission techniques has been developed. A single-carbon-fiber composite based on a polyester matrix, has been used as a simple model. The occurrence of fiber-breakage during tensile loading tests has been observed by a polarized light microscope and concurrently detected by a resonant acoustic probe. The resonant probe has been used as a trigger for the reading of fiber failure events. Single acoustic emission events from a wide-band probe has been recorded for FFT Analysis. The single-fiber specimen, having a unique failure mode, has advantages for the standardization of AE techniques for the quantitative analysis of failures in polymer-composite materials. The same procedure can be exploited to investigate other failure modes namely, fiber matrix solidus debonding and matrix cracking. (C) 1998 Elsevier Science Ltd. All rights reserved.