Effects of singlet and triplet energy transfer to molecular dopants in polymer light-emitting diodes and their usefulness in chromaticity tuning

被引:37
作者
Higgins, RWT [1 ]
Monkman, AP
Nothofer, HG
Scherf, U
机构
[1] Univ Durham, Dept Phys, Durham, England
[2] Max Planck Inst Polymer Res, Mainz, Germany
关键词
D O I
10.1063/1.1389070
中图分类号
O59 [应用物理学];
学科分类号
摘要
Efficient, white emission with Commission Internationale de L'Eclairage coordinates of 0.33, 0.42 is demonstrated from polymer light-emitting diodes operating at high brightness. An amino endcapped polyfluorene derivative doped with rubrene was used as the active layer, in combination with a poly(3,4-ethylenedioxythiophene) hole transport layer. Luminescence reaches 14950 Cd/m(2) at a current density of 150 mA/cm(2), and the maximum external quantum efficiency measured 1.05% for a bias voltage of 9.0 V. We observe a fall in external quantum efficiency relative to the undoped device, which we ascribe to an increased singlet-triplet annihilation rate at the dopant sites. (C) 2001 American Institute of Physics.
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页码:857 / 859
页数:3
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