Rh particle growth on insulator substrates: RHEED study

被引:14
作者
Masek, K
Matolin, V
机构
[1] Dept. Electronics and Vacuum Phys., Faculty of Mathematics and Physics, Charles University, 18000 Prague 8
关键词
clusters; epitaxy; reflection; high energy electron diffraction (RHEED);
D O I
10.1016/S0040-6090(96)08550-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Three-dimensional Rh particle catalysts were prepared by heteroepitaxial growth on alpha-Al2O3 (0001),NaCl (001) and KCl (001) substrates. During the deposition, the particle structure and orientation were characterised by Reflection High Energy Electron Diffraction (RHEED). It was shown that ar sufficiently high temperatures the Rh particles conserve the symmetry of tile substrate (hexagonal in the case of alpha-Al2O3 (0001) and cubic for (001) NaCl and (001) KCl substrates). Ar lower temperatures the layers are disordered or partially disordered.
引用
收藏
页码:330 / 335
页数:6
相关论文
共 16 条
[1]  
BRUNA JC, 1993, CZECHOSLOVAK J PHYSI, V43, P9
[2]  
DOERING DL, 1982, J CATAL, V73, P104, DOI 10.1016/0021-9517(82)90085-9
[3]   UHV STUDIES OF THE INTERACTION OF CO WITH SMALL SUPPORTED METAL PARTICLES, NI MICA [J].
DOERING, DL ;
DICKINSON, JT ;
POPPA, H .
JOURNAL OF CATALYSIS, 1982, 73 (01) :91-103
[4]   CRYSTALLOGRAPHIC STRUCTURE AND CHEMISORPTION ACTIVITY OF PALLADIUM MICA MODEL CATALYSTS .2. TEMPERATURE PROGRAMMED DESORPTION STUDY OF CO CHEMISORPTION ON WELL-DEFINED PALLADIUM PARTICLES [J].
GILLET, E ;
CHANNAKHONE, S ;
MATOLIN, V .
JOURNAL OF CATALYSIS, 1986, 97 (02) :437-447
[5]   CRYSTALLOGRAPHIC STRUCTURE AND CHEMISORPTION ACTIVITY OF PALLADIUM/MICA MODEL CATALYSTS .1. STRUCTURE AND MORPHOLOGY OF SMALL PALLADIUM PARTICLES [J].
GILLET, MF ;
CHANNAKHONE, S .
JOURNAL OF CATALYSIS, 1986, 97 (02) :427-436
[6]   REFLECTION HIGH-ENERGY ELECTRON-DIFFRACTION STUDY OF GROWTH AND MODIFICATION OF SMALL-PARTICLE MODEL CATALYST - PD ON MICA [J].
GILLET, MF ;
MATOLIN, V .
JOURNAL OF CRYSTAL GROWTH, 1993, 134 (1-2) :75-80
[7]   THE ADSORPTION AND CATALYTIC-OXIDATION OF CARBON-MONOXIDE ON EVAPORATED PALLADIUM PARTICLES [J].
LADAS, S ;
POPPA, H ;
BOUDART, M .
SURFACE SCIENCE, 1981, 102 (01) :151-171
[8]  
LAGALLY MG, 1989, NATO ASI SER B-PHYS, V188, P139
[9]   STUDY OF THE GROWTH OF RHODIUM PARTICLES ON DIFFERENT SUBSTRATES [J].
MASEK, K ;
MATOLIN, V ;
GILLET, M .
THIN SOLID FILMS, 1995, 260 (02) :252-258
[10]  
MASEK K, IN PRESS