A New [3]Rotaxane Molecular Machine Based on a Dibenzylammonium Ion and a Triazolium Station

被引：75

作者：

Jiang, Yi ^{[1
,2
]}

Guo, Jia-Bin ^{[1
,2
]}

Chen, Chuan-Feng ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 10049, Peoples R China

来源：

ORGANIC LETTERS | 2010年 / 12卷 / 19期

基金：

中国国家自然科学基金;

关键词：

COMPLEXATION; ROTAXANES; PARAQUAT; MOTION; HOST;

D O I：

10.1021/ol101920b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel two-station [3]rotaxane molecular machine based on triptycene-derived macrotricyclic host was conveniently synthesized by the click reaction and methylation of the subsequent 1,2,3-tiazole group. The shuttle process of the [3]rotaxane molecular machine can be reversibly achieved by acid base control.

引用

页码：4248 / 4251

页数：4

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