Synthesis and characterization of Na6Cd7S10: A new framework sulfide with 1-D channels containing 12- and 16-member rings and a sulfide anion in an umbrella-like geometry

被引：18

作者：

Axtell, EA ^{[1
]}

Kanatzidis, MG ^{[1
]}

机构：

[1] MICHIGAN STATE UNIV,CTR FUNDAMENTAL MAT RES,E LANSING,MI 48824

来源：

CHEMISTRY OF MATERIALS | 1996年 / 8卷 / 07期

关键词：

D O I：

10.1021/cm9506060

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The new ternary cadmium sulfide compound Na6Cd7S10 exhibits a tunneled three-dimensional framework, with a sulfur atom in an ''umbrella'' geometry. Its lattice contains numerous ''built-in'' cadmium vacancies which are believed to give rise to its interesting light-absorbing and -emitting properties.

引用

页码：1350 / &

页数：4

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