Dye-sensitized solar cells based on quaternary phosphonium ionic liquids as electrolytes

被引:16
作者
Kunugi, Yoshihito [1 ]
Hayakawa, Hideyuki [1 ]
Tsunashima, Katsuhiko [2 ]
Sugiya, Masashi [2 ]
机构
[1] Tokai Univ, Fac Engn, Dept Appl Chem, Hiratsuka, Kanagawa 2591292, Japan
[2] Nippon Chem Ind Co Ltd, Organ Chem R & D Dept, Koto Ku, Tokyo 1368515, Japan
关键词
D O I
10.1246/bcsj.80.2473
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Dye-sensitized solar cells using quaternary phosphomurn ionic liquids as their electrolytes have been successfully fabricated. Of these, the best device performance was achieved by using triethyl(pentyl)phosphonium bis(trifluoromethyl-sulfonyl)amide, whose energy conversion efficiencies were determined to be 1.2% and 3.8% under full (AM 1.5, 100 mW cm(-2)) and low intensity (7 MW cm(-2)) sunlight illumination, respectively. Interestingly, the energy conversion efficiencies for the quaternary phosphonium ionic liquid electrolytes are higher than those for the corresponding quaternary ammonium ionic liquids.
引用
收藏
页码:2473 / 2475
页数:3
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