INTRINSIC MICROPOROSITY;
SURFACE-AREA;
GAS SORPTION;
NETWORKS;
SPIROBIFLUORENE;
D O I:
10.1039/c1py00217a
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Conjugated, microporous polymers based on a spirobifluorene core were synthesized by Suzuki polycondensation of the tetra-bromospirobifluorene with benzene diboronic acid and/or thiophene diboronic acid. The optical properties (absorption and emission spectra) and the gas sorption properties (N(2) and CO(2)) are analyzed and discussed.