Tunable absorption and emission wavelength in conjugated microporous polymers by copolymerization

被引:49
作者
Brandt, Jessica [1 ]
Schmidt, Johannes [2 ]
Thomas, Arne [2 ]
Epping, Jan Dirk [2 ]
Weber, Jens [1 ]
机构
[1] Max Planck Inst Colloids & Interfaces, Dept Colloid Chem, D-14424 Potsdam, Germany
[2] Tech Univ Berlin, Dept Chem, D-10587 Berlin, Germany
关键词
INTRINSIC MICROPOROSITY; SURFACE-AREA; GAS SORPTION; NETWORKS; SPIROBIFLUORENE;
D O I
10.1039/c1py00217a
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Conjugated, microporous polymers based on a spirobifluorene core were synthesized by Suzuki polycondensation of the tetra-bromospirobifluorene with benzene diboronic acid and/or thiophene diboronic acid. The optical properties (absorption and emission spectra) and the gas sorption properties (N(2) and CO(2)) are analyzed and discussed.
引用
收藏
页码:1950 / 1952
页数:3
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