High-Performance Inverted Polymer Solar Cells with Solution-Processed Titanium Chelate as Electron-Collecting Layer on ITO Electrode

被引:302
作者
Tan, Zhan'ao [1 ,2 ]
Zhang, Wenqing [1 ,2 ]
Zhang, Zhiguo [1 ]
Qian, Deping [1 ,2 ]
Huang, Ye [1 ]
Hou, Jianhui [1 ]
Li, Yongfang [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] N China Elect Power Univ, State Key Lab Alternate Elect Power Syst Renewabl, New & Renewable Energy Beijing Key Lab, Beijing 102206, Peoples R China
关键词
polymer solar cells; inverted structure; titanium chelate; electron-collecting layer; OPEN-CIRCUIT VOLTAGE; PHOTOVOLTAIC CELLS; EFFICIENT;
D O I
10.1002/adma.201104863
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-performance inverted polymer solar cells (PSCs) with solution-processed titanium chelate TIPD as electron collecting layer are reported. The power conversion efficiency (PCE) of the inverted PSC with a-TIPD buffer layer with thermal annealing at 150 C for 10 min reached 7.4% under the illumination of AM1.5, 100 mW/cm2, which is increased by 16% in comparison with that (6.4%) of the device in the conventional structure. The PCE of 7.4% is the highest among the inverted PSCs reported so far in the literature.
引用
收藏
页码:1476 / 1481
页数:6
相关论文
共 42 条
[1]  
[Anonymous], 1992, HIGH RESOLUTION XPS
[2]   THE STRETCHING FREQUENCIES OF METAL-OXYGEN DOUBLE BONDS [J].
BARRACLOUGH, CG ;
LEWIS, J ;
NYHOLM, RS .
JOURNAL OF THE CHEMICAL SOCIETY, 1959, (NOV) :3552-3555
[3]   INFRARED SPECTRA OF METAL ISOPROPOXIDES [J].
BELL, JV ;
HEISLER, J ;
TANNENBAUM, H ;
GOLDENSON, J .
ANALYTICAL CHEMISTRY, 1953, 25 (11) :1720-1724
[4]   Polymer solar cells with enhanced open-circuit voltage and efficiency [J].
Chen, Hsiang-Yu ;
Hou, Jianhui ;
Zhang, Shaoqing ;
Liang, Yongye ;
Yang, Guanwen ;
Yang, Yang ;
Yu, Luping ;
Wu, Yue ;
Li, Gang .
NATURE PHOTONICS, 2009, 3 (11) :649-653
[5]   Development of Novel Conjugated Donor Polymers for High-Efficiency Bulk-Heterojunction Photovoltaic Devices [J].
Chen, Junwu ;
Cao, Yong .
ACCOUNTS OF CHEMICAL RESEARCH, 2009, 42 (11) :1709-1718
[6]   Recent Progress in Polymer Solar Cells: Manipulation of Polymer: Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells [J].
Chen, Li-Min ;
Hong, Ziruo ;
Li, Gang ;
Yang, Yang .
ADVANCED MATERIALS, 2009, 21 (14-15) :1434-1449
[7]   Self-Assembled and Cross-Linked Fullerene Interlayer on Titanium Oxide for Highly Efficient Inverted Polymer Solar Cells [J].
Cheng, Yen-Ju ;
Cao, Fong-Yi ;
Lin, Wei-Cheng ;
Chen, Chiu-Hsiang ;
Hsieh, Chao-Hsiang .
CHEMISTRY OF MATERIALS, 2011, 23 (06) :1512-1518
[8]   Combination of Indene-C60 Bis-Adduct and Cross-Linked Fullerene Interlayer Leading to Highly Efficient Inverted Polymer Solar Cells [J].
Cheng, Yen-Ju ;
Hsieh, Chao-Hsiang ;
He, Youjun ;
Hsu, Chain-Shu ;
Li, Yongfang .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (49) :17381-17383
[9]   Flexible multilayer inverted polymer light-emitting diodes with a gravure contact printed Cs2CO3 electron injection layer [J].
Chung, Dae-Young ;
Leem, Dong-Seok ;
Bradley, Donal D. C. ;
Campbell, Alasdair J. .
APPLIED PHYSICS LETTERS, 2011, 98 (10)
[10]   Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes [J].
de Jong, MP ;
van IJzendoorn, LJ ;
de Voigt, MJA .
APPLIED PHYSICS LETTERS, 2000, 77 (14) :2255-2257