Polymeric precursor synthesis of alumina containing manganese oxide

被引:13
作者
Gouvea, D [1 ]
Villalobos, RL [1 ]
Capocchi, JDT [1 ]
机构
[1] Univ Sao Paulo, Escola Politecn, Dept Met & Mat Engn, BR-05508900 Sao Paulo, Brazil
来源
ADVANCED POWDER TECHNOLOGY | 1999年 / 299-3卷
关键词
alumina; powder synthesis; alpha-Al2O3; crystallization;
D O I
10.4028/www.scientific.net/MSF.299-300.91
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Ceramic materials have been successfully prepared by using organic precursors. Synthesized compounds include, for example, tin dioxide, zinc oxide, niobates, ferrites and silicates. Among all the additives that can promote alumina densification, manganese oxide is especially effective in the absence of liquid phase. Addition of 7 mor % of manganese during aluminum oxide preparation by organic precursors synthesis promotes alpha-Al2O3 crystallization at 900 degrees C. The resulting powder presents a high specific surface area. Manganese oxide has not been detected by X-ray diffraction analysis even when high manganese concentration was used, suggesting that segregation occurs to the interfaces, similarly to the Mn doped-SnO2 powder prepared by polymeric method.
引用
收藏
页码:91 / 96
页数:6
相关论文
共 19 条
  • [1] BOSCHI AO, 1988, INF INT, V20, P16
  • [2] SINTERING AND GRAIN GROWTH OF ALPHA-ALUMINA
    CAHOON, HP
    CHRISTENSEN, CJ
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1956, 39 (10) : 337 - 344
  • [3] INITIAL SINTERING OF ALUMINA AND HEMATITE
    COBLE, RL
    [J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1958, 41 (02) : 55 - 62
  • [4] Cutler I.B., 1959, Kinetics of High Temperature Process Part III, P120
  • [5] Thermal stability of transition phases in zirconia-doped alumina
    Djuricic, B
    Pickering, S
    Glaude, P
    McGarry, D
    Tambuyser, P
    [J]. JOURNAL OF MATERIALS SCIENCE, 1997, 32 (03) : 589 - 601
  • [6] THE DENSIFICATION AND MICROSTRUCTURAL DEVELOPMENT OF AL2O3 WITH MANGANESE OXIDE ADDITION
    ERKALFA, H
    MISIRLI, Z
    DEMIRCI, M
    TOY, C
    BAYKARA, T
    [J]. JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1995, 15 (02) : 165 - 171
  • [7] GOUVEA D, 1993, EUR J SOL STATE INOR, V30, P915
  • [8] Gouvea D, 1996, EUR J SOL STATE INOR, V33, P1015
  • [9] Gouvea D, 1996, EUR J SOL STATE INOR, V33, P343
  • [10] HARMER M, 1979, BRIT CERAM TRANS J, V78, P22