Self-assembly of two discrete polynuclear iron(II) metallomacrocycles from a ligand containing two 2,2′:6′, 2"-terpyridine binding domains

被引：50

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Smith, CB ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 08期

关键词：

2,2 ': 6 ',2 ''-terpyridine; metallomacrocycle; iron(II);

D O I：

10.1016/S1387-7003(03)00168-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homoditopic ligand L contains two tpy metal-binding domains and reacts with iron(II) chloride to form two multinuclear metallomacrocycles having [3 + 3] and [4 + 4] metal-ligand stoichiometries. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：1011 / 1013

页数：3

共 13 条

[1] CARGILLTHOMPSON AM, 1997, COORDIN CHEM REV, V160, P1
[2] SYNTHESIS AND COORDINATION BEHAVIOR OF 6',6''-BIS(2-PYRIDYL)-2,2'-4,4''-2'',2'''-QUATERPYRIDINE - BACK-TO-BACK 2,2'-6',2''-TERPYRIDINE
CONSTABLE, EC
WARD, MD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1990, (04): : 1405 - 1409
[3] Pentaerythritol-based metallodendrimers
Constable, EC
Housecroft, CE
Cattalini, M
Phillips, D
[J]. NEW JOURNAL OF CHEMISTRY, 1998, 22 (02) : 193 - 200
[4] Metal-directed assembly of a box-like structure
Constable, EC
Schofield, E
[J]. CHEMICAL COMMUNICATIONS, 1998, (03) : 403 - 404
[5] Newkome GR, 2002, CHEM-EUR J, V8, P2946, DOI 10.1002/1521-3765(20020703)8:13<2946::AID-CHEM2946>3.0.CO
[6] 2-M
[7] Synthesis of two covalently linked bis(2,2′:6′,2"-terpyridine) (terpy) chelating ligands with different length spacers, comparison of the crystal structures of their mononuclear nickel(II) complexes, and kinetic and mechanistic studies of the reaction of one ligand with [Fe(terpy)2]2+
Priimov, GU
Moore, P
Maritim, PK
Butalanyi, PK
Alcock, NW
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (04): : 445 - 449
[8] Monitoring the iron(II)-induced self-assembly of preorganized tritopic ligands by electrospray mass spectrometry: Unique formation of metallomacrocycles
Romero, FM
Ziessel, R
DupontGervais, A
VanDorsselaer, A
[J]. CHEMICAL COMMUNICATIONS, 1996, (04) : 551 - 553
[9] SAUVAGE JP, 1996, COMPREHENSIVE COORDI, V9
[10] 4′-functionalized 2,2′:6′,2"-terpyridines as building blocks for supramolecular chemistry and nanoscience
Schubert, US
Eschbaumer, C
Hien, O
Andres, PR
[J]. TETRAHEDRON LETTERS, 2001, 42 (28) : 4705 - 4707

← 1 2 →