Mild electrophilic trifluoromethylation of secondary and primary aryl- and alkylphosphines using hypervalent iodine(III)-CF3 reagents

被引：119

作者：

Eisenberger, Patrick ^{[1
]}

Kieltsch, Iris ^{[1
]}

Armanino, Nicolas ^{[1
]}

Togni, Antonio ^{[1
]}

机构：

[1] ETH, Swiss Fed Inst Technol, Dept Chem & Appl Biosci, CH-8093 Zurich, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2008年 / 13期

关键词：

D O I：

10.1039/b801424h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A direct, mild and efficient trifluoromethylation of primary and secondary phosphines is achieved with easily accessible, cheap hypervalent iodine compounds acting as electrophilic CF(3)-transfer reagents.

引用

页码：1575 / 1577

页数：3

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