Separation of an enantiomorph and its racemate by distillation: Strong chiral recognizing ability of trifluorolactates

被引:70
作者
Katagiri, T [1 ]
Yoda, C [1 ]
Furuhashi, K [1 ]
Ueki, K [1 ]
Kubota, T [1 ]
机构
[1] IBARAKI UNIV, DEPT MAT SCI, HITACHI, IBARAKI 316, JAPAN
关键词
D O I
10.1246/cl.1996.115
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Trifluorolactate experienced modification of its enantiomeric excess by fractional distillation. Quantitative studies have shown that the separation of an enantiomorph and its racemate is due to a change in boiling points that depend on the enantiomeric excess of the compound. Such a change in the boiling point was not seen in the case of the non fluorinated lactate.
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页码:115 / 116
页数:2
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