A bis(cyclopalladated) tetranuclear derivative of methyl ferrocenyl ketone azine: [{Pd[(eta(5)-C5H5)Fe(eta(5)-C5H3)CMe=N]Cl(PPh(3))}(2)]

被引：16

作者：

Bosque, R

Lopez, C

Sales, J

Solans, X

Silver, J

机构：

[1] UNIV BARCELONA, DEPT QUIM INORGAN, E-08028 BARCELONA, SPAIN

[2] UNIV BARCELONA, DEPT CRISTALLOG MINERAL & DIPOSITS MINERALS, E-08028 BARCELONA, SPAIN

[3] UNIV ESSEX, DEPT BIOL & CHEM SCI, COLCHESTER CO4 3SQ, ESSEX, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 15期

关键词：

D O I：

10.1039/dt9960003195

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The bis(cyclopalladated) tetranuclear compound [{Pd[(eta(5) -C5H5)Fe(eta(5)-C5H3)CMe=N]Cl(PPh3)}(2)] has been prepared and characterized. Proton and P-31 NMR spectra reveal the presence of four diastereomers in solution. The crystal structure of the meso form has been determined by X-ray crystallography. This confirms the existence of two five-membered palladacycles with a sigma(Pd-C-sp2,C-ferrocene) bond. Electrochemical studies, based on cyclic voltammetry, and Mossbauer spectra are also reported.

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页码：3195 / 3200

页数：6

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